Niveditha & Palanisamy (2025): Upcycling iron-rich industrial waste into a carbon-sequestering composite binder through optimized carbonation curing for structural applications
Niveditha M. and Palanisamy T., IN: International Journal of Environmental Studies, https://doi.org/10.1080/15623599.2025.2556259
Background: Steel production generates large quantities of mill scale, a by-product rich in iron oxides, with global generation estimated at 13.5 million tons annually. Simultaneously, Portland cement production, essential for concrete, contributes nearly 8% of global CO₂ emissions, highlighting the urgent need for low-carbon alternatives. Iron carbonate (FeCO₃), typically regarded as a corrosion product, offers an underexplored opportunity for deliberate synthesis in binders to achieve both structural performance and CO₂ sequestration. Repurposing mill scale into carbon-sink binders thus provides a dual pathway for waste valorization and climate change mitigation, while advancing circular economy and industrial symbiosis principles. Methods: A composite binder was developed using mill scale, fly ash, metakaolin, and limestone, with oxalic acid employed as a chelating agent to promote iron dissolution and carbonate formation.