Liu et al. (2026): Electrified reversible surface mineralization of CO₂ for direct air capture
Zeyan Liu, Huajie Ze, Bosi Peng, Charles B. Musgrave III, Mohammad K. Shehab, Hyun Seung Jung, Hengzhou Liu, Kent O. Kirlikovali, William A. Goddard III, Omar K. Farha, Ke Xie and Edward H. Sargent, IN: Nature Energy, https://doi.org/10.1038/s41560-026-01989-9
Electrified CO₂ capture and release from air offers net-negative emissions, but today’s liquid-carbonate-based systems have a high energy cost (6–10 GJ per ton of CO₂), and organic sorbents are oxygen sensitive. Here the authors report electrified CO₂ surface mineralization/demineralization capture/release, wherein an inorganic capture sorbent, MnO₂, is electrochemically reduced/activated to generate Mn(III), which mineralizes CO₂ to form MnOOCO₂H (operando Raman); the process is reversed under oxidative potential.