Neubrand et al. (2025): Activation and Fixation of Atmospheric CO2 through a 1,2,3-Triazole-based Mesoionic Carbene-Borane Adduct
Maren Neubrand, Jessica Stubbe, Richard Rudolf, Robert R. M. Walter, Maite Nößler, Biprajit Sarkar IN: Chemistry A European Journal, 2025, https://doi.org/10.1002/chem.202403942
Capturing atmospheric CO2 and converting it to valuable chemicals are important goals in contemporary science. Here, the authors present a simple, transition metal-free triazolylidene-borane adduct that can capture atmospheric CO2 and convert it to formate. Several key intermediates were isolated and characterized by a combination of multinuclear NMR spectroscopy, IR spectroscopy and single-crystal X-ray diffraction. The first closed cycle for the conversion of CO2 to formic acid by using the aforementioned triazolylidene-borane compound is also presented.