Hegarty et al. (2026): Structure–Property Relationships for Moisture-Swing Direct Air Capture
John Hegarty, Michael L. Barsoum, Megan Burrill, Cayden Shen, Omar K. Farha, Sossina M. Haile, Vinayak P. Dravid, IN: Environmental Science & Technology, https://doi.org/10.1021/acs.est.5c16820
Efficient, low-cost atmospheric CO₂ capture is essential for scaling negative-emission technologies. Moisture-swing carbon capture─which adsorbs CO₂ from dry air and releases it under humid conditions─offers a low-energy alternative, yet the structure–property relationships governing its performance remain underexplored. Here, the authors systematically investigate humidity-driven capture on strong-base ion-exchange resins (IERs), varying polymer backbones (acrylic vs styrenic), ammonium functionality (Type I vs Type II), pore architecture (gel-type vs macroporous), and counteranion (dibasic phosphate vs carbonate) across 10 commercial resins. Thermodynamic and kinetic behaviors were assessed via closed-loop cycling with ambient CO₂ at 20–70% RH. Morphological and chemical properties were characterized by SEM/EDS, N₂ sorption, NMR cryoporometry, and solid-state NMR and FTIR spectroscopies.