Fakhraddinfakhriazar et al. (2026): Stability of Adsorbents for Direct Air Capture (DAC): Challenges and Perspectives
Salar Fakhraddinfakhriazar, Cristhian Molina-Fernández and Grégoire Léonard, IN: Energy & Fuels, https://doi.org/10.1021/acs.energyfuels.5c05460
Direct air capture (DAC) technologies, particularly adsorption-based systems, are advancing rapidly as a form of negative emission technologies (NETs). DAC technologies represent a promising engineering approach to addressing diffuse CO₂ emissions and provide several deployment advantages, including flexibility and scalability. However, a critical yet often overlooked challenge of adsorption-based DAC is the limited stability of CO₂ sorbent materials, which undermines sustainability and hinders large-scale deployment. While most research has focused on developing adsorbents with high CO₂ selectivity and capacity, stability remains a crucial criterion, investigated in some studies through multicycle testing and exposure to accelerated degradation environments. This review provides a brief overview of DAC adsorbent types, followed by a detailed analysis of existing studies on the stability of solid sorbents under DAC operating conditions, highlighting key findings and research gaps.